Ismail Ibrahem

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Ismail Ibrahem was born in 1972 in Bagdad, Iraq. He got his M Sc in 2004 from Stockholm University, and finished his PhD in asymmetric organocatalysis at Stockholm University (with Prof. A. Cordova) in 2007. He then moved to Boston College, US for a post doc in the field of asymmetric metal catalysis (Molybdenum catalyzed olefin metathesis) with Prof. Amir H. Hoveyda and in close collaboration with Prof. Richard R. Schrock (Nobel Laurate), at MIT, US.
Returning to Sweden, he became Associate Professor at Mid Sweden University, Sundsvall.

Forskningsområden

1-Water Chemistry and fibre modification and derivativation.

2-Selective Catalysis and Asymmetric Synthesis

Our research interests: The fields of organic synthesis, organometallic chemistry, Organocatalysis Dual catalysis, and asymmetric catalysis.



Publikationer

Artiklar i tidskrifter

Afewerki, S. , Ma, G. , Ibrahem, I. , Liu, L. , Sun, J. & Cordova, A. (2015). Highly Enantioselective Control of Dynamic Cascade Transformations by Dual Catalysis : Asymmetric Synthesis of Polysubstituted Spirocyclic Oxindoles. ACS Catalysis, vol. 5: 2, ss. 1266-1272.

Duan, R. , Ibrahem, I. , Edlund, H. & Norgren, M. (2014). Acid-Catalyzed Synthesis of Foamed Materials from Renewable Sources. Industrial & Engineering Chemistry Research, vol. 53: 45, ss. 17597-17603.

Afewerki, S. , Guangning, M. , Ibrahem, I. & Cordova, A. (2014). Highly enantioselective organo/metal cooperative catalysis for construction of spirocyclopentaneoxindoles. Abstract of Papers of the American Chemical Society, vol. 248

Ibrahem, I. , Ma, G. , Afewerki, S. & Córdova, A. (2013). Palladium/Chiral Amine Co-catalyzed Enantioselective beta-Arylation of alpha,beta-Unsaturated Aldehydes. Angewandte Chemie International Edition, vol. 52: 3, ss. 878-882.

Ma, G. , Afewerki, S. , Deiana, L. , Palo-Nieto, C. , Liu, L. , Sun, J. , Ibrahem, I. & Córdova, A. (2013). A palladium/chiral amine co-catalyzed enantioselective dynamic cascade reaction : Synthesis of polysubstituted carbocycles with a quaternary carbon stereocenter. Angewandte Chemie International Edition, vol. 52: 23, ss. 6050-6054.

M, Y. , Ibrahem, I. , Hasegawa, M. , Schrock, R. & Hoveyda, H. (2012). Enol Ethers as Substrates for Efficient Z- and Enantioselective Ring-Opening/Cross-Metathesis Reactions Promoted by Stereogenic-at-Mo Complexes; Utility in Chemical Synthesis and Mechanistic Attributes. Journal of the American Chemical Society, vol. 134: 5, ss. 2788-2799.

Ma, G. , Lin, S. , Ibrahem, I. , Kubik, G. , Liu, L. , Sun, J. & Cordova, A. (2012). Achiral Co-Catalyst Induced Switches in Catalytic Asymmetric Reactions on Racemic Mixtures (RRM) : From Stereodivergent RRM to Stereoconvergent Deracemization by Combination of Hydrogen Bond Donating and Chiral Amine Catalysts. Advanced Synthesis and Catalysis, vol. 354: 14-15, ss. 2865-2872.

Afewerki, S. , Ibrahem, I. , Rydfjord, J. , Breistein, P. & Córdova, A. (2012). Direct Regiospecific and Highly Enantioselective Intermolecular α-Allylic Alkylation of Aldehydes By Combination of Transition Metal and amine Catalysts. Chemistry - A European Journal, vol. 18: 10, ss. 2972-2977.

Ibrahem, I. , Breistein, P. & Córdova, A. (2012). One-pot three-component highly selective synthesis of homoallylboronates by using metal-free catalysis. Chemistry - A European Journal, vol. 18: 17, ss. 5175-5179.

Ma, G. , Bartoszewicz, A. , Ibrahem, I. & Córdova, A. (2011). Highly Enantioselective Co-Catalytic Direct Aldol reactions by Combination of Hydrogen-Bond Donating and Acyclic Amino Acid Catalysts. Advanced Synthesis and Catalysis, vol. 353: 17, ss. 3114-3122.

Ibrahem, I. , Breistein, P. & Córdova, A. (2011). One-Pot Three-Component Catalytic Enantioselective Synthesis of Homoallylboronates. Angewandte Chemie International Edition, vol. 50: 50, ss. 12036-12041.

Deiana, L. , Dziedzic, P. , Zhao, G. , Vesely, J. , Ibrahem, I. , Rios, R. , Sun, J. & Cordova, A. (2011). Catalytic Asymmetric Aziridination of alpha,beta-Unsaturated Aldehydes. Chemistry - A European Journal, vol. 17: 28, ss. 7904-7917.

Ibrahem, I. , Santoro, S. , Himo, F. & Cordova, A. (2011). Enantioselective Conjugate Silyl Additions to alpha,beta-Unsaturated Aldehydes Catalyzed by Combination of Transition Metal and Chiral Amine Catalysts. Advanced Synthesis and Catalysis, vol. 353: 2-3, ss. 245-252.

Afewerki, S. , Breistein, P. , Pirttilä, K. , Deiana, L. , Dziedzic, P. , Ibrahem, I. & Córdova, A. (2011). Catalytic Enantioselective beta-Alkylation of alpha,beta-Unsaturated Aldehydes by Combination of Transition-Metal- and Aminocatalysis: Total Synthesis of Bisabolane Sesquiterpenes. Chemistry - A European Journal, vol. 17: 32, ss. 8784-8788.

Zhao, G. , Ullah, F. , Deiana, L. , Lin, S. , Zhang, Q. , Sun, J. , Ibrahem, I. , Dziedzic, P. & et al. (2010). Dynamic kinetic asymmetric transformation (DYKAT) by combined amine and transition metal catalyzed enantioselective cycloisomerization. Chemistry - A European Journal,

Konferensbidrag

Duan, R. , Norgren, M. , Hedenström, E. , Ibrahem, I. & Edlund, H. (2013). New approaches toward producing foamed materials from renewable sources.. .

Ibrahem, I. , Afewerki, S. , Breistein, P. & Córdova, A. (2012). One-pot three-component catalytic asymmetric synthesis of homoallylboronates. I ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. Vol 243. (ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY). S. 889-INOR-

Córdova, A. , Ibrahem, I. , Afewerki, S. , Breistein, P. , Deiana, L. , Zhao, G. , Dziedzic, P. , Pirttilä, K. & et al. (2010). TOC-Trends in Organic Chemistry : Selective Catalysis. .